Obviously, the limit of the method differs between laboratories dependent upon the extent to which background levels of radioactivity can be reduced.
Amongst accelerator laboratories there has been mooted the theoretical possibility of extended range dating to 75 000 yr , at present this seems difficult to attain because of the problems in accurately differentiating between ions that mimic the mass and charge characteristics of the C14 atom.
d14C represents the per mille depletion in sample carbon 14 prior to isotopic fractionation correction and is measured by: D14C represents the 'normalized' value of d14C.
By measuring the activity of a background sample, the normal radioactivity present while a sample of unknown age is being measured can be accounted for and deducted.
In an earlier section we mentioned that the limit of the technique is about 55-60 000 years.
The Oxalic acid standard was made from a crop of 1955 sugar beet. The isotopic ratio of HOx I is -19.3 per mille with respect to (wrt) the PBD standard belemnite (Mann, 1983). T designation SRM 4990 C) was made from a crop of 1977 French beet molasses.
The Oxalic acid standard which was developed is no longer commercially available. In the early 1980's, a group of 12 laboratories measured the ratios of the two standards.
The terms "%Modern", or "pm C" and D14C are shown related in this diagram along with the Radiocarbon age in years BP (Before 1950 AD).
If the reservoir corrected conventional radiocarbon age calculated is within the past 200 years, it should by convention be termed 'Modern' (Stuiver and Polach, 192).
Beukens (1994) for instance has stated that this means the limit of the range for his Isotrace laboratory is 60 000 yr which is very similar to the conventional range.
Figure 1: This gif shows the comparison in radioactivity between a sample, or unknown (green area) , a modern standard (dark blue) and a background (small red peaks) derived from beta decay. A radiocarbon measurement, termed a conventional radiocarbon age (or CRA) is obtained using a set of parameters outlined by Stuiver and Polach (1977), in the journal Radiocarbon.
Should the activity of the sample be indistinguishable from the background activity at 1 standard deviation, it is released as background.
Samples whose age falls between modern and background and are given finite ages.
This is calculated through careful measurement of the residual activity (per gram C) remaining in a sample whose age is Unknown, compared with the activity present in Modern and Background samples. Thus 1950, is year 0 BP by convention in radiocarbon dating and is deemed to be the 'present'.